A UHV multi-step protocol with Ni(acac)2 precursor produces continuous single-layer Ni3(HITP)2 on HOPG showing 30-degree rotated hexagonal lattice by STM, plus controlled AA-stacked bilayer.
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To date, however, the experimental synthesis has largely resulted in SL c-MOFs on metal substrates, whose intrinsic properties are strongly screened due to substrate hybridization
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In vacuo synthesis of single-layer Ni3(HITP)2 on HOPG surface using metallo-organic precursor
A UHV multi-step protocol with Ni(acac)2 precursor produces continuous single-layer Ni3(HITP)2 on HOPG showing 30-degree rotated hexagonal lattice by STM, plus controlled AA-stacked bilayer.