Treating the cosmological constant as pressure in black hole thermodynamics yields an extended dictionary with enthalpy, thermodynamic volume, and chemical-like phase transitions including Van der Waals behavior, reentrant transitions, and triple points.
Teitelboim, The Cosmological constant as a thermodynamic black hole parameter , Phys
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Black hole chemistry: thermodynamics with Lambda
Treating the cosmological constant as pressure in black hole thermodynamics yields an extended dictionary with enthalpy, thermodynamic volume, and chemical-like phase transitions including Van der Waals behavior, reentrant transitions, and triple points.