The author revises the chemical potential to include the P V_i term, μ_i = U_i - T S_i + P V_i, and redefines the work term in the first law for open systems.
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Revisiting the First, Second and Combined Laws of Thermodynamics
The author revises the chemical potential to include the P V_i term, μ_i = U_i - T S_i + P V_i, and redefines the work term in the first law for open systems.