UV photodissociation of hot H3+ yields a cold H2+ product and a hot H2 product, with the ground-state channel attributed to non-adiabatic transfer at the avoided crossing seam.
Such wavelengths mainly probe the photodissociation from ex- cited vibrational states of H + 3 that are populated follow- ing its formation in the ion source plasma
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Photodissociation as a probe of the H$_3^+$ avoided crossing seam
UV photodissociation of hot H3+ yields a cold H2+ product and a hot H2 product, with the ground-state channel attributed to non-adiabatic transfer at the avoided crossing seam.