FAPbI3 forms a metastable twin-domain network below ~100 K selected by shallow tilt energetics and slowing FA reorientation, reconciling low-temperature observations.
Phase Transitions and Dynamics in Mixed Three- and Low-dimensional Lead Halide Perovskites.Chemical Reviews2024,124, 2281–2326
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Kinetically Arrested Twin-Domain State in Formamidinium Lead Iodide
FAPbI3 forms a metastable twin-domain network below ~100 K selected by shallow tilt energetics and slowing FA reorientation, reconciling low-temperature observations.