A two-compartment model yields analytical expressions for biosensor equilibration time and required sample volume as functions of the Damköhler number.
Newman, The fundamental principles of current distribution and mass transport in electrochemical cells, EACH V 6 (1973) 187–352
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Sample volume as a key design parameter in affinity-based biosensors
A two-compartment model yields analytical expressions for biosensor equilibration time and required sample volume as functions of the Damköhler number.