The kinetic stability of the T' phase in MoS2 arises from S-S repulsive interactions that raise barriers for nucleation and grain boundary motion, with sulfur vacancies migrating away from the stable ZZ-Mo|- interface rather than accelerating transformation.
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Phase transformation kinetics in MoS2 governed by S-S repulsive interactions and defect-interface compatibility
The kinetic stability of the T' phase in MoS2 arises from S-S repulsive interactions that raise barriers for nucleation and grain boundary motion, with sulfur vacancies migrating away from the stable ZZ-Mo|- interface rather than accelerating transformation.