In cage compounds the effective Grüneisen parameter is temperature-dependent and exhibits two approximate regimes, with measured crossovers at about 11 K in LaB6 and 10.5 K in LaPt4Ge12.
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Gr\"uneisen rule in cubic rare-earth cage systems : the examples of LaB$_6$ and LaPt$_{4}$Ge$_{12}$
In cage compounds the effective Grüneisen parameter is temperature-dependent and exhibits two approximate regimes, with measured crossovers at about 11 K in LaB6 and 10.5 K in LaPt4Ge12.