Hydrogen segregation at triple junctions in nanocrystalline Pd is stronger than at grain boundaries, and the authors' model predicts up to a threefold increase in hydrogen density at fine grain sizes.
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Interstitial Solute Segregation at Triple Junctions: Implications for the Hydrogen Storage Properties of Nanomaterials
Hydrogen segregation at triple junctions in nanocrystalline Pd is stronger than at grain boundaries, and the authors' model predicts up to a threefold increase in hydrogen density at fine grain sizes.