Treating the cosmological constant as pressure in black hole thermodynamics yields an extended dictionary with enthalpy, thermodynamic volume, and chemical-like phase transitions including Van der Waals behavior, reentrant transitions, and triple points.
The Extended Thermodynamic Properties of Taub-NUT/Bolt-AdS spaces
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We investigate the extended thermodynamic properties of higher-dimensional Taub-NUT/Bolt-AdS spaces where a cosmological constant is treated as a pressure. We find a general form for thermodynamic volumes of Taub-NUT/Bolt-AdS black holes for arbitrary dimensions. Interestingly, it is found that the Taub-NUT-AdS metric has a thermodynamically stable range when the total number of dimensions is a multiple of 4 (4, 8, 12, ...). We also explore their phase structure and find the first order phase transition holds for higher-dimensional cases.
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Black hole chemistry: thermodynamics with Lambda
Treating the cosmological constant as pressure in black hole thermodynamics yields an extended dictionary with enthalpy, thermodynamic volume, and chemical-like phase transitions including Van der Waals behavior, reentrant transitions, and triple points.