The authors assign CrSBr emission bands at 720, 850, 920, and 990 nm to Cr3+ monomer, dark-state pair, ferromagnetic trimer, and interlayer tetramer magnetic polaronic excitons.
Above 75 K, the peak intensity gradually decreased, exhibiting a blue- shift at 100 K followed by a red -shift until stabilizing near 726 nm at 200 K (Fig S5a and Fig S5c)
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Magnetic polaronic exciton in A-type 2D van der Waals bulk material CrSBr
The authors assign CrSBr emission bands at 720, 850, 920, and 990 nm to Cr3+ monomer, dark-state pair, ferromagnetic trimer, and interlayer tetramer magnetic polaronic excitons.