The inversion of magnetic and orbital ordering temperatures in RVO3 arises when orbital ordering is governed by quadrupolar super-exchange and the magnetic structure is set by the rank-0 dipolar spin-spin interaction.
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Origin of the transitions inversion in rare-earth vanadates
The inversion of magnetic and orbital ordering temperatures in RVO3 arises when orbital ordering is governed by quadrupolar super-exchange and the magnetic structure is set by the rank-0 dipolar spin-spin interaction.