Sub-resonant charge cycling of NV centers arises from phonon-assisted anti-Stokes excitation, with low-energy acoustic phonons near the ZPL and a 43 meV mode at longer wavelengths contributing most.
Lax, The franck-condon principle and its application to crystals, J
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Phonon-assisted charge-cycling of nitrogen-vacancy centres in diamond
Sub-resonant charge cycling of NV centers arises from phonon-assisted anti-Stokes excitation, with low-energy acoustic phonons near the ZPL and a 43 meV mode at longer wavelengths contributing most.