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Ionic relaxations were performed using the BFGS algorithm until forces dropped below 0.05 eV/Å (0.08 eV/Å for Ni)

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Self-consistent Hessian-level meta-generalized gradient approximation

physics.chem-ph · 2026-04-08 · conditional · novelty 7.0

The paper introduces ϑ-PBE, a non-empirical Hessian-level meta-GGA that distinguishes one-electron density limits better than standard iso-orbital indicators and provides a roadmap for self-consistent PAW implementation.

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  • Self-consistent Hessian-level meta-generalized gradient approximation physics.chem-ph · 2026-04-08 · conditional · none · ref 1

    The paper introduces ϑ-PBE, a non-empirical Hessian-level meta-GGA that distinguishes one-electron density limits better than standard iso-orbital indicators and provides a roadmap for self-consistent PAW implementation.