Isostructural CeCN5 and TbCN5 show Ce in 4+ and Tb in 3+ oxidation states, producing insulating versus metallic behavior because the polymeric C-N network distributes the extra electron from Ce.
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Electronic structure and oxidation states in high-pressure synthesized isostructural CeCN$_5$ and TbCN$_5$
Isostructural CeCN5 and TbCN5 show Ce in 4+ and Tb in 3+ oxidation states, producing insulating versus metallic behavior because the polymeric C-N network distributes the extra electron from Ce.