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Al0.68Sc0.32N/SiC based metal-ferroelectric-semiconductor capacitors operating up to 1000 {\deg}C

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abstract

Ferroelectric (Fe) materials-based devices show great promise for non-volatile memory applications, yet few demonstrate reliable operation at elevated temperatures. In this work, we demonstrate Ni/Al0.68Sc0.32N/4H-SiC metal-ferroelectric-semiconductor capacitors for high-temperature non-volatile memory applications. Our 30-nm thick ferroelectric Al0.68Sc0.32N film grown on SiC exhibits stable and robust ferroelectric switching up to 1000{\deg}C. The coercive field decreases linearly from -6.4/+11.9 MV cm-1 at room temperature to -3.1/+7.8 MV cm-1 at 800{\deg}C, further reducing to -2.5 MV cm-1 at 1000{\deg}C. At 600{\deg}C, the devices achieve remarkable reliability with ~2000 endurance cycles and over at least 100 hours of retention with negligible polarization loss. At 800{\deg}C, the devices retain data for at least 10,000 seconds and exceed 400 write cycles. Our results further highlight the potential for ferroelectric AlScN thin-films particularly when paired with SiC semiconductor substrates for high-temperature non-volatile memory.

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representative citing papers

A Thermodynamic Theory of Proximity Ferroelectricity

cond-mat.mtrl-sci · 2025-01-09 · conditional · novelty 5.0

Internal electric fields in ferroelectric/non-ferroelectric bilayers renormalize the Landau coefficients so that both layers acquire nearly equal remanent polarization and coercive fields, enabling 'proximity switching'.

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  • A Thermodynamic Theory of Proximity Ferroelectricity cond-mat.mtrl-sci · 2025-01-09 · conditional · none · ref 24 · internal anchor

    Internal electric fields in ferroelectric/non-ferroelectric bilayers renormalize the Landau coefficients so that both layers acquire nearly equal remanent polarization and coercive fields, enabling 'proximity switching'.