Vacancy ordering along the growth direction reduces the local symmetry of Mn[Co] Prussian Blue Analogues from cubic to tetragonal while the average structure remains cubic.
Nature 490, 472–473 (2012)
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Symmetry breaking in Prussian Blue Analogues via growth--guided local ordering of hexacyanometallate vacancies
Vacancy ordering along the growth direction reduces the local symmetry of Mn[Co] Prussian Blue Analogues from cubic to tetragonal while the average structure remains cubic.