Ba3TbRu2O9 shows cooperative antiferromagnetic ordering of Tb4+ (L=0, S=7/2) and Ru4+ (S=1) moments below 9.5 K, with terbium in an unusual tetravalent state.
Elemental mapping obtained from EDS analysis: (b) oxygen (O K), (c) terbium (Tb L), (d) ruthenium (Ru L), and (e) barium (Ba L)
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Unconventional S-orbital state of Tb and cooperative Ru(4d)-Tb(4f) spin-ordering in strongly correlated 4d-4f system, Ba3TbRu2O9
Ba3TbRu2O9 shows cooperative antiferromagnetic ordering of Tb4+ (L=0, S=7/2) and Ru4+ (S=1) moments below 9.5 K, with terbium in an unusual tetravalent state.