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Rise and fall of the old quantum theory

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abstract

The old quantum theory of Bohr and Sommerfeld was abandonned for the wrong reason. Its contradictions were caused not by the orbit concept but by a mental barrier--the inconceivability that an electron might collide with the atomic nucleus. Removing that barrier resolves the theory's main failures--incorrect orbital momenta, He atom, H2+ molecule ion. The inclusion of electron oscillations through the nucleus--a concept called "Coulomb oscillator"--renders the old quantum theory consistent with quantum mechanics (although devoid of wave character). The triple success of the Bohr-Sommerfeld model is its correct description of the H atom (and one-electron ions) concerning (1) the energy levels Enl, (2) the orbital angular momenta Lnl--if corrected as Lnl^2 = l(l+1) hbar^2 and with the Coulomb oscillator included--and (3) the orbits' space quantization--with (Lnl)z = ml hbar. These achievements are succinctly represented by the principal, angular and magnetic quantum numbers (n, l, ml) and visualized by orbital ellipse geometry--major axis, vertex curvature, and tilt angle, respectively. Orbit geometry also accounts for the average orbit size. Moreover, the Coulomb oscillator provides a natural explanation of (isotropic) hyperfine interaction. The shortcomings of the old quantum theory lie in its neglect of three properties of particles--their spin, their wave nature and their quantum statistics. These deficiencies notwithstanding, the visual appeal of the Bohr-Sommerfeld model remains a pedagogical asset to complement the abstract character of quantum mechanics.

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Second Quantization for the Kepler Problem

math-ph · 2025-07-15 · conditional · novelty 5.0

The Hilbert space of spin-1/2 hydrogen bound states is unitarily equivalent, as an SU(2)xSU(2) representation, to the Hilbert space of a massless left-handed Weyl field on R x S^3, and the same holds for their fermionic Fock spaces.

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  • Second Quantization for the Kepler Problem math-ph · 2025-07-15 · conditional · none · ref 4 · internal anchor

    The Hilbert space of spin-1/2 hydrogen bound states is unitarily equivalent, as an SU(2)xSU(2) representation, to the Hilbert space of a massless left-handed Weyl field on R x S^3, and the same holds for their fermionic Fock spaces.