If a reaction network has a weakly reversible deficiency zero realization for all rate constants, that realization is unique and can be found by an algorithm.
An algorithm for finding weakly reversible deficiency zero realizations of polynomial dynamical systems
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abstract
Systems of differential equations with polynomial right-hand sides are very common in applications. On the other hand, their mathematical analysis is very challenging in general, due to the possibility of complex dynamics: multiple basins of attraction, oscillations, and even chaotic dynamics. Even if we restrict our attention to mass-action systems, all of these complex dynamical behaviours are still possible. On the other hand, if a polynomial dynamical system has a weakly reversible deficiency zero ($WR_0$) realization, then its dynamics is known to be remarkably simple: oscillations and chaotic dynamics are ruled out and, up to linear conservation laws, there exists a single positive steady state, which is asymptotically stable. Here we describe an algorithm for finding $WR_0$ realizations of polynomial dynamical systems, whenever such realizations exist.
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Weakly reversible deficiency zero realizations of reaction networks
If a reaction network has a weakly reversible deficiency zero realization for all rate constants, that realization is unique and can be found by an algorithm.