Chemical vapor transport growth of AgCrSe2 introduces Cl off-stoichiometry with composition Ag1-xCr(Se2-yCly) (x≈y≈0.08) that suppresses the Neel temperature to 46 K, while optimized Ag/Se self-flux growth recovers the stoichiometric 58 K transition and saturation field.
M.; Schmidt, M.; Fartab, D.; Mackenzie, A
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Resolving growth-induced off-stoichiometry in AgCrSe$_2$ single crystals
Chemical vapor transport growth of AgCrSe2 introduces Cl off-stoichiometry with composition Ag1-xCr(Se2-yCly) (x≈y≈0.08) that suppresses the Neel temperature to 46 K, while optimized Ag/Se self-flux growth recovers the stoichiometric 58 K transition and saturation field.