On Cu(111), dynamical screening from the substrate reduces or quenches the local spin moments of adsorbed transition-metal phthalocyanines in an orbital-filling-dependent way.
Local moment dynamics and screening effects in doped charge-transfer insulators
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abstract
By means of Dynamical Mean-Field Theory we investigate the spin response function of a model for correlated materials with d- or f-electrons hybridized with more delocalized ligand orbitals. We point out the existence of two different processes responsible for the dynamical screening of local moments of the correlated electrons. Studying the local spin susceptibility we identify the contribution of the "direct" magnetic exchange and of an "indirect" one mediated by the itinerant uncorrelated orbitals. In addition, we characterize the nature of the dynamical screening processes in terms of different classes of diagrams in the hybridization-expansion contributing to the density-matrix. Our analysis suggests possible ways of estimating the relative importance of these two classes of screening processes in realistic calculations for correlated materials.
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Dynamical Screening of Local Spin Moments at Metal-Molecule Interfaces
On Cu(111), dynamical screening from the substrate reduces or quenches the local spin moments of adsorbed transition-metal phthalocyanines in an orbital-filling-dependent way.