The change of a diffusion activation barrier with temperature equals the variance of site energies, minus the variance of transition-state energies, plus a kinetic correlation term (Eq. 5).
Tunable interstitial and vacancy diffusivity by chemical ordering control in CrCoNi medium-entropy alloy,
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Statistical Mechanics of Thermal Diffusion in Rough Energy Landscapes
The change of a diffusion activation barrier with temperature equals the variance of site energies, minus the variance of transition-state energies, plus a kinetic correlation term (Eq. 5).