Open CRN behavior and thermodynamics, including local detailed balance and entropy production, emerge to leading order from closed CRNs via time-scale and abundance separations for arbitrary stoichiometries.
The two systems exchange energy, while the total energy of the supersystem𝐸≡𝐸 𝐴 +𝐸 𝐵 remains conserved, with𝐸 𝐴 and𝐸 𝐵 being the energies of system𝐴and𝐵, re- spectively
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Emergence of Open Chemical Reaction Network Thermodynamics within Closed Systems
Open CRN behavior and thermodynamics, including local detailed balance and entropy production, emerge to leading order from closed CRNs via time-scale and abundance separations for arbitrary stoichiometries.