BN doping renders the planar-to-Dewar isomerization asymmetric via a B-C stabilized metastable intermediate whose transition state resembles an S0/S1 conical intersection, and targeted substitution red-shifts S1 while boosting oscillator strength and Dewar yield.
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Explicit inclusion of molecular vibrations in few-emitter plasmonic lasers produces intensity resonances controlled by Stokes shift, drive strength, and emitter count.
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Asymmetric Planar-to-Dewar Isomerisation in BN-Doped Naphthalene: Mechanistic Implications for Molecular Solar Thermal Storage
BN doping renders the planar-to-Dewar isomerization asymmetric via a B-C stabilized metastable intermediate whose transition state resembles an S0/S1 conical intersection, and targeted substitution red-shifts S1 while boosting oscillator strength and Dewar yield.
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Vibrationally Induced Resonances in Lasing
Explicit inclusion of molecular vibrations in few-emitter plasmonic lasers produces intensity resonances controlled by Stokes shift, drive strength, and emitter count.