Alloyed interlayers mixing core and shell atoms plus vacancies in InAs/CdSe QDs restore band alignment and delocalized states while abrupt interfaces cause charge imbalance and gap collapse.
(33) Verma, P.; Truhlar, D
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Interfacial Reconstructions and Engineering in III-V@II-VI Core-Shell Quantum Dots
Alloyed interlayers mixing core and shell atoms plus vacancies in InAs/CdSe QDs restore band alignment and delocalized states while abrupt interfaces cause charge imbalance and gap collapse.