For any substance where the solid is less dense than the liquid, the Helmholtz driving force for solidification is smaller in isochoric than in isobaric conditions, supplying a thermodynamic explanation for enhanced supercooling stability and a bulk-data-derived stability number.
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A Thermodynamic Analysis of Enhanced Metastability in Isochoric Supercooled Liquids
For any substance where the solid is less dense than the liquid, the Helmholtz driving force for solidification is smaller in isochoric than in isobaric conditions, supplying a thermodynamic explanation for enhanced supercooling stability and a bulk-data-derived stability number.