Synthesis and characterization of AOsO4 (A=K, Rb, Cs) show antiferromagnetic transitions at 36.9 K and 21 K for K and Rb, a structural transition at 152.5 K for Cs without magnetic order, and reduced Os moments attributed to orbital contributions.
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Crystal structure and the magnetic properties of the 5d transition metal oxide AOsO4 (A = K, Rb, Cs)
Synthesis and characterization of AOsO4 (A=K, Rb, Cs) show antiferromagnetic transitions at 36.9 K and 21 K for K and Rb, a structural transition at 152.5 K for Cs without magnetic order, and reduced Os moments attributed to orbital contributions.