Layered metastable polymorphs of MgZrN2 and MgHfN2 were synthesized by topochemical ion exchange from Li2MN2 precursors, with optical absorption onset near 2.0 eV.
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Ion exchange synthesizes layered polymorphs of MgZrN$_2$ and MgHfN$_2$, two metastable semiconductors
Layered metastable polymorphs of MgZrN2 and MgHfN2 were synthesized by topochemical ion exchange from Li2MN2 precursors, with optical absorption onset near 2.0 eV.