Experimental measurements reveal large inverse Cl-KIEs (down to 0.492) in CID of three chlorohydrocarbons that decrease with collision energy from 0-60 eV, with both normal and inverse effects observed for dichloromethane.
Tureček, The use of kinetic isotope effects for the determination of internal energy distributions in isolated transient species in the gas phase, Int
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Energy-dependent normal and unusually large inverse chlorine kinetic isotope effects of simple chlorohydrocarbons in collision-induced dissociation by gas chromatography-tandem mass spectrometry
Experimental measurements reveal large inverse Cl-KIEs (down to 0.492) in CID of three chlorohydrocarbons that decrease with collision energy from 0-60 eV, with both normal and inverse effects observed for dichloromethane.