First interstellar detection of HNSO with column density (8 ± 1)×10^13 cm^{-2} and abundance ~6×10^{-10} relative to H2, proposed to form via NSO + H on icy grains.
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Hydrogen tunneling makes H-abstraction reactions by C2H, OH, and CN competitive in TMC-1 despite low individual rates, affecting aromatic abundance predictions.
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