In ternary PEG mixtures, fluorescence lifetime follows a linear mixing rule with polymer proportion, and free volume theory captures the trend semi-quantitatively but leaves open questions about its precise application.
Kovacs, Applicability of the free volume concept on relax- ation phenomena in the glass transition range, Rheologica Acta 5, 262 (1966)
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Response of fluorescent molecular rotors in ternary macromolecular mixtures
In ternary PEG mixtures, fluorescence lifetime follows a linear mixing rule with polymer proportion, and free volume theory captures the trend semi-quantitatively but leaves open questions about its precise application.