Treating the cosmological constant as pressure in black hole thermodynamics yields an extended dictionary with enthalpy, thermodynamic volume, and chemical-like phase transitions including Van der Waals behavior, reentrant transitions, and triple points.
Never Judge a Black Hole by Its Area
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abstract
Christodoulou and Rovelli have shown that black holes have large interiors that grow asymptotically linearly in advanced time, and speculated that this may be relevant to the information loss paradox. We show that there is no simple relation between the interior volume of an arbitrary black hole and its horizon area. That is, the volume enclosed is not necessarily a monotonically increasing function of the surface area.
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Black hole chemistry: thermodynamics with Lambda
Treating the cosmological constant as pressure in black hole thermodynamics yields an extended dictionary with enthalpy, thermodynamic volume, and chemical-like phase transitions including Van der Waals behavior, reentrant transitions, and triple points.