The volume-based bubble size distribution diverges as v^(-2/3) at small sizes, and the bubble formation free energy in a Lennard-Jones liquid needs an extra term linear in radius beyond the capillarity approximation.
Giri , author M
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Molecular-sized bubbles in a liquid: free energy of formation beyond the capillarity approximation
The volume-based bubble size distribution diverges as v^(-2/3) at small sizes, and the bubble formation free energy in a Lennard-Jones liquid needs an extra term linear in radius beyond the capillarity approximation.