Ultrafast spectroscopy and modeling show conical intersections driven by vibronic modes enable rapid 4T2 to 2E intersystem crossing in Cr(acac)3 despite weak spin-orbit coupling.
Excited-state dynamics of [Mn(im)(CO)3(phen)]+: PhotoCORM, catalyst, luminescent probe?
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Conical Intersections Enable Ultrafast Molecular Spin Control in a Chromium Complex
Ultrafast spectroscopy and modeling show conical intersections driven by vibronic modes enable rapid 4T2 to 2E intersystem crossing in Cr(acac)3 despite weak spin-orbit coupling.