Asymmetric 12-fold F coordination in predicted high-pressure RbBF5 activates Rb 4p inner-shell electrons via orbital splitting, enabling their participation in bonding.
The smaller radius of Rb than that of Cs, Ba and Ra might make its 4p-electron activation rarely occurs even at extremely high pressure in Rb-F binary
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Activation of Inner-Shell 4p-Orbital Electrons of Rubidium Driven by Asymmetric Coordination at High Pressure
Asymmetric 12-fold F coordination in predicted high-pressure RbBF5 activates Rb 4p inner-shell electrons via orbital splitting, enabling their participation in bonding.