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From Wavefunction Sign Structure to Static Correlation

cond-mat.str-el · 2025-11-03 · unverdicted · novelty 6.0

A variational nodal partition decomposes correlation energy into E_sym containing dynamic and strong correlation and E_stat isolating the antisymmetric sign-structure component as an energy penalty from node constraint.

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  • From Wavefunction Sign Structure to Static Correlation cond-mat.str-el · 2025-11-03 · unverdicted · none · ref 33

    A variational nodal partition decomposes correlation energy into E_sym containing dynamic and strong correlation and E_stat isolating the antisymmetric sign-structure component as an energy penalty from node constraint.