Wertheim TPT1 is rendered exact in 1D for divalent patchy rods via exact density-unbonded fraction relations and bonding free energy, revealing monotonic-to-oscillatory pair-correlation decay separated by a Fisher-Widom line plus Widom and ECO lines that vanish in the sticky limit.
Santos ,\ @noop title A Concise Course on the Theory of Classical Liquids
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Thermodynamic and structural behavior of one-dimensional divalent patchy hard rods: Wertheim's first-order thermodynamic perturbation theory versus exact results
Wertheim TPT1 is rendered exact in 1D for divalent patchy rods via exact density-unbonded fraction relations and bonding free energy, revealing monotonic-to-oscillatory pair-correlation decay separated by a Fisher-Widom line plus Widom and ECO lines that vanish in the sticky limit.