Dilution in polar hosts blue-shifts carbene-metal-amide triplet emission by up to 210 meV through suppressed triplet diffusion plus host-guest electrostatics.
Initial data taken at 300 K before cooling the film to 10 K, “Final
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Environmental Control of Triplet Emission in Donor-Bridge-Acceptor Organometallics
Dilution in polar hosts blue-shifts carbene-metal-amide triplet emission by up to 210 meV through suppressed triplet diffusion plus host-guest electrostatics.