In phase-field simulations of hydrogen permeation, stronger grain boundary trapping raises hydrogen flux along the boundaries by increasing occupancy gradients, so trapping and diffusion cooperate.
Fundamentals of Hydrogen Embrittlement
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Modeling the effect of grain boundary diffusivity and trapping on hydrogen transport using a phase-field compatible formulation
In phase-field simulations of hydrogen permeation, stronger grain boundary trapping raises hydrogen flux along the boundaries by increasing occupancy gradients, so trapping and diffusion cooperate.