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Stochastic Cluster Expansion for Excited State Energies

physics.chem-ph · 2026-05-01 · unverdicted · novelty 7.0

Stochastic cluster expansion is extended to excited states by reconstructing energy differences from reduced-rank calculations on a minimal frontier chemical subspace treated exactly plus stochastic sampling of the orbital environment.

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  • Stochastic Cluster Expansion for Excited State Energies physics.chem-ph · 2026-05-01 · unverdicted · none · ref 61

    Stochastic cluster expansion is extended to excited states by reconstructing energy differences from reduced-rank calculations on a minimal frontier chemical subspace treated exactly plus stochastic sampling of the orbital environment.