Na3FeCr(PO4)3 undergoes an order-disorder transition near 350 K driven by Na-vacancy redistribution from ordered monoclinic to disordered rhombohedral symmetry without framework reconstruction.
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Order-disorder transition and Na-ion redistribution in NASICON-type Na$_3$FeCr(PO$_4$)$_3$
Na3FeCr(PO4)3 undergoes an order-disorder transition near 350 K driven by Na-vacancy redistribution from ordered monoclinic to disordered rhombohedral symmetry without framework reconstruction.