Derives a cusp criterion in asymmetry-coupling parameter space determining when an adiabatic Marcus Hamiltonian supports a local Hamiltonian bottleneck with NHIMs on the lower sheet.
Tilting and squeezing: phase space geometry of Hamiltonian saddle-node bifurcation and its influence on chemical reaction dynamics
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Phase Space Bottlenecks in an Adiabatic Marcus Hamiltonian: Cusp Geometry, NHIMs, and Mixed Valence Electron Transfer
Derives a cusp criterion in asymmetry-coupling parameter space determining when an adiabatic Marcus Hamiltonian supports a local Hamiltonian bottleneck with NHIMs on the lower sheet.