Mobile diffuse ions in a low-permittivity Stern layer create a forward inner electro-osmotic flow, making the apparent zeta potential exceed the surface potential, especially at large slip length and high salt.
slip plane
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Enhanced zeta potentials caused by surface ion mobilities
Mobile diffuse ions in a low-permittivity Stern layer create a forward inner electro-osmotic flow, making the apparent zeta potential exceed the surface potential, especially at large slip length and high salt.