Symplectic capacities and non-squeezing may impose geometric constraints on reaction rates near saddles that are not captured by total phase-space volume or flux alone.
A formula to compute the microcanoni- cal volume of reactive initial conditions in transition state theory
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Symplectic Constraints in Classical Reaction Dynamics: From Gromov's Camel to Reaction Rates
Symplectic capacities and non-squeezing may impose geometric constraints on reaction rates near saddles that are not captured by total phase-space volume or flux alone.