The central Raman peak observed in cubic and tetragonal phases of metal halide perovskites is attributed primarily to disorder-induced second-order acoustic-phonon Raman scattering, drawing support from analogous behavior in other disordered semiconductor systems.
Halogen-NH + 2 interaction, temperature-induced phase transition, and ordering in (NH 2CHNH2)PbX3 (X = Cl, Br, I) hybrid per- ovskites
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Phonon Interactions in Metal Halide Perovskites elucidated by Raman Scattering
The central Raman peak observed in cubic and tetragonal phases of metal halide perovskites is attributed primarily to disorder-induced second-order acoustic-phonon Raman scattering, drawing support from analogous behavior in other disordered semiconductor systems.