Adapted lab laser-photolysis yields for adsorbed benzene to PDR starlight give surface photolysis fractions below 1 percent even at high field strengths, so this channel is negligible for small hydrocarbons.
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The Photolysis of Aromatic Hydrocarbons Adsorbed on the Surfaces of Cosmic Dust Grains
Adapted lab laser-photolysis yields for adsorbed benzene to PDR starlight give surface photolysis fractions below 1 percent even at high field strengths, so this channel is negligible for small hydrocarbons.