Retrievals on six isolated brown dwarfs yield near-solar C/O (0.51-0.63), metallicities, and 12C/13C ratios (91-155) supporting molecular cloud fragmentation origin.
ExoMol line lists III: An improved hot rotation-vibration line list for HCN and HNC
1 Pith paper cite this work. Polarity classification is still indexing.
abstract
A revised rotation-vibration line list for the combined hydrogen cyanide (HCN) / hydrogen isocyanide (HNC) system is presented. The line list uses {\it ab initio} transition intensities calculated previously (Harris et al., ApJ, 2002, 578, 657) and extensive datasets of recently measured experimental energy levels (Mellau, J. Chem. Phys. and J. Mol. Spectrosc. 2010-2011). The resulting line list has significantly more accurate wavelengths than previous ones for these systems. An improved value for the separation between HCN and HNC is adopted leading to an approximately 25%\ lower predicted thermal population of HNC as a function of temperature in the key 2000 to 3000 K region. Temperature-dependent partition functions and equilibrium constants are presented. The line lists are validated by comparison with laboratory spectra and are presented in full as supplementary data to the article and at \url{www.exomol.com}.
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astro-ph.EP 1years
2026 1verdicts
UNVERDICTED 1representative citing papers
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The ESO SupJup Survey XI. Atmospheric properties of six isolated M- and L-type dwarfs with CRIRES+
Retrievals on six isolated brown dwarfs yield near-solar C/O (0.51-0.63), metallicities, and 12C/13C ratios (91-155) supporting molecular cloud fragmentation origin.