A symmetric start, a symmetric light pulse, and a return to the starting state together forbid net photocurrent, so real photovoltaic currents must break at least one of these conditions.
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Photovoltaic Effect from the Viewpoint of Time-reversal Symmetry
A symmetric start, a symmetric light pulse, and a return to the starting state together forbid net photocurrent, so real photovoltaic currents must break at least one of these conditions.