Time-suspension pulse sequences outperform spectroscopic ones for dipolar decoupling in dense spin solids with local magnetic-field disorder, as shown by NMR experiments and numerical simulations.
Frame Change Technique for Phase Transient Cancellation
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abstract
The precise control of complex quantum mechanical systems can unlock applications ranging from quantum simulation to quantum computation. Controlling strongly interacting many-body systems often relies on Floquet Hamiltonian engineering that is achieved by fast switching between Hamiltonian primitives via external control. For example, in our solid-state NMR system, we perform quantum simulation by modulating the natural Hamiltonian with control pulses. As the Floquet heating errors scale with the interpulse delay, $\delta t$, it is favorable to keep $\delta t$ as short as possible, forcing our control pulses to be short duration and high power. Additionally, high-power pulses help to minimize undesirable evolution from occurring during the duration of the pulse. However, such pulses introduce an appreciable phase-transient control error, a form of unitary error. In this work, we detail our ability to diagnose the error, calibrate its magnitude, and correct it for $\pi/2$-pulses of arbitrary phase. We demonstrate the improvements gained by correcting for the phase transient error, using a method which we call the ``frame-change technique'', in a variety of experimental settings of interest. Given that the correction mechanism adds no real control overhead, we recommend that any resonance probe be checked for these phase transient control errors, and correct them using the frame-change technique.
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Decoupling Dipolar Interactions in Dense Spin Ensembles
Time-suspension pulse sequences outperform spectroscopic ones for dipolar decoupling in dense spin solids with local magnetic-field disorder, as shown by NMR experiments and numerical simulations.